UConn’s scientific glassblower, Daryl Smith, fashions specialized glassware like this rotary evaporator bump trap for hundreds of faculty and graduate students to use in teaching and research.
More from UConn Chemistry
Thursday, February 16th, 2017
04:45 PM - 05:45 PM
Storrs CampusChem A203
Graduate Student Seminar
"Derivatization With Cost-Effective Fmoc-Amino Acid-Osu Reagents for Peptide Fragmentation Mechanism Study"
Refreshments will be served at 4:30pm. All are welcome.
Wednesday, February 22nd, 2017
04:30 PM - 05:30 PM
Storrs CampusChem A203
"Reliable and Reversible Molecular Linkages for Chemical Biology"
M. G. Finn
Host: Xudong Yao
Refreshments will be served at 4:15pm. All are welcome.
Thursday, February 23rd, 2017
09:30 AM - 10:30 AM
Storrs CampusIMS 20
Cold Thoughts on Perovskite Fever
Dr. Tao Xu
Northern Illinois University
The latest progress in solution process-based organic-inorganic hybrid perovskites solar cells is reshaping the growth pattern of any previous photovoltaic technologies and has raised a storm of research fever. However, despite the success in boosting efficiency, it also appears high time to inject an intense dose of cold thoughts into this globally-spreading âperovskite feverâ, because perovskite solar cells are still facing several critical challenges. Prominently, these hybrid perovskites suffer from the materials instability in moisture, the use of environment-hazardous lead, the costly and unstable complex organics as hole transport materials, the use of precious metals as back cathode, the hysteresis in current-voltage scans, the tricky engineering of good-quality perovskite films. Moreover, there are still some missing puzzle pieces for a comprehensive basic science understanding of the extraordinary excellence in both charge transport and light harvesting in hybrid perovskite materials so as to provide crucial fundamental clues that can navigate future research towards the approach of better photovoltaic materials by designing. In this talk, I will present some of our work on tackling these challenges. First, I will show that nickel, as an industrial commodity metal with work function of 5.1 eV, can replace gold as the back cathode in perovskite solar cells with competitive performance to gold-cathoded cells, and the work function and the conductivity of the cathode are both fundamentally important factors impacting the photovoltage and fill factor of the perovskite solar cells. Furthermore, I will also show that when partial iodides in CH3NH3PbI3 are replaced with pseudohalide ions thiocyanate (SCN-), the resulting SCN-containing perovskite films strikingly rival the conventional CH3NH3PbI3 films in terms of moisture-tolerance as evidenced by their tolerance in 95% relative humidity in air for over 4 hours without significant degradation, in contrast to pristine CH3NH3PbI3 films that degraded in less than 1.5 hours. The solar cells based on the SCN-containing perovskite thin films exhibit efficiency comparable to that of CH3NH3PbI3-based cells fabricated in the same way. In this talk, I will also present our recent discovery of a new kind of electron-lattice interaction in semiconductors, namely electron-rotor interaction discovered in hybrid perovskite materials using isotope effects and the unusual optical and electronic properties of perovskite materials under high pressure condition. Moreover, I will also discuss our discovery of some abnormal optoelectronic properties of hybrid perovskites under high pressure, which modulates their bond length and bond angle. These fundamental studies provide a new coordination in the mechanistic foundation needed for better materials by designing.
Tao Xu joined the faculty of Northern Illinois University in August 200